Synthesis, Molecular Structure from the X-ray Diffraction Data of the Powder (1E,1'E)-1,1'-(1,4-Phenylene)Bis(N-(Adamantan-1-yl)methanimine)

  • Shukkur A. Hamed Department of Chemistry, College of Education for Pure Science, University Of Anbar, Al-Anbar, Iraq
Keywords: Powder X-ray diffraction, Adamantan-1-ylamine, Bis Schiff base

Abstract

The title compound was synthesized by 2:1 condensation between adamantan-1-ylamine and benzene-1,4- dicarbaldehyde in n-BuOH and produced a good yield 87% of new bis Schiff base. The compound skeleton was affirmed by FTIR, 1H NMR, LC-MS, and X-ray powder diffraction. The structure was solved by a parallel tempering process and refined by using Rietveld refinement. Two adamantan-1-ylimino groups are connected in the anti-positions to the planar central 1,4-dimethylbenzene group. All rings of the adamantyl group possess normal chair conformation.

Published
2021-04-29
How to Cite
Hamed, S. A. (2021). Synthesis, Molecular Structure from the X-ray Diffraction Data of the Powder (1E,1’E)-1,1’-(1,4-Phenylene)Bis(N-(Adamantan-1-yl)methanimine). Iraqi Journal of Science, 62(4), 1066-1076. https://doi.org/10.24996/ijs.2021.62.4.3
Section
Chemistry